The coordination chemistry of guanidines and guanidinates

被引：513

作者：

Bailey, PJ ^{[1
]}

Pace, S ^{[1
]}

机构：

[1] Univ Edinburgh, Dept Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

来源：

COORDINATION CHEMISTRY REVIEWS | 2001年 / 214卷

关键词：

nitrogen ligands; guanidines; coordination chemistry;

D O I：

10.1016/S0010-8545(00)00389-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Species containing the Y-shaped CN, unit have recently attracted increasing attention as electronically and sterically flexible ligands. Neutral guanidines [(R2N)(2)C=NR], guanidinates(-1) [(RN)(2)CNR2](-) and guanidinates(2-) [(RN)(2)C=NR](2-) are capable of exhibiting a variety of coordination modes and a range of donor properties leading to compatibility with a remarkably wide range of metal ions from all parts of the periodic table. The coordination chemistry of these species is reviewed up to July 2000, and aspects of their electronic structures and metal-ligand bonding characteristics discussed. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：91 / 141

页数：51

共 71 条

[1] Aluminum alkyl complexes containing guanidinate ligands
Aeilts, SL
Coles, MP
Swenson, DG
Jordan, RF
Young, VG
[J]. ORGANOMETALLICS, 1998, 17 (15) : 3265 - 3270
[2] Guanidinates as chelating anionic ligands for early, middle and late transition metals:: syntheses and crystal structures of [Ti{η2-(NPh)2CNEt2}2Cl2], [Ru{η2-(NPh)2CNHPh}3] and [Pt{η2-(NPh)2CNHPh}2]
Bailey, PJ
Grant, KJ
Mitchell, LA
Pace, S
Parkin, A
Parsons, S
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (12): : 1887 - 1891
[3] Synthesis and structure of [Sb{(Pr(i)N)(2)CNHPr(i)}{(Pr(i)N)(2)CNPr(i)}]; A distorted trigonal-bipyramidal antimony(III) complex with a helical hydrogen-bond network
Bailey, PJ
Gould, RO
Harmer, CN
Pace, S
Steiner, A
Wright, DS
[J]. CHEMICAL COMMUNICATIONS, 1997, (13) : 1161 - 1162
[4] Synthesis and structure of [{(Me(3)Si)(2)N}(2)Cd{(PhN)(3)C}Li-2 center dot 3thf]; An unusual heterobimetallic co-complex containing three different metal coordination environments
Bailey, PJ
Mitchell, LA
Raithby, PR
Rennie, MA
Verhorevoort, K
Wright, DS
[J]. CHEMICAL COMMUNICATIONS, 1996, (11) : 1351 - 1352
[5] Guanidines as neutral monodentate ligands; syntheses and crystal structures of [Co{PhN=C(NHPh)(2)}(2)Cl-2] and [Ag{PhN=C(NHPh)(2)}][SO3CF3]
Bailey, PJ
Grant, KJ
Pace, S
Parsons, S
Stewart, LJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (22): : 4263 - 4266
[6] Guanidine anions as chelating ligands; Syntheses and crystal structures of [Rh(eta-C(5)Me(5)){eta(2)-(NPh)(2)CNHPh}Cl] and [Ru(eta-MeC(6)H(4)Pr(i)-p)-{eta(2)-(NPh)(2)CNHPh}Cl]
Bailey, PJ
Mitchell, LA
Parsons, S
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (13): : 2839 - 2841
[7] THE FIRST TRIAZATRIMETHYLENEMETHANE DIANION - CRYSTAL-STRUCTURE OF DILITHIO-TRIPHENYLGUANIDINE LI-2[C(NPH)(3)] AS ITS TETRAHYDROFURAN SOLVATE
BAILEY, PJ
BLAKE, AJ
KRYSZCZUK, M
PARSONS, S
REED, D
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (16) : 1647 - 1648
[8] A new bridging ligand for the [Mo-2](4+) dimer: Syntheses and x-ray crystal structures of the redox pair [Mo-2{mu-eta(2)-(NPh)(2)CNHPh}(4)](0/+)
Bailey, PJ
Bone, SF
Mitchell, LA
Parsons, S
Taylor, KJ
Yellowlees, LJ
[J]. INORGANIC CHEMISTRY, 1997, 36 (05) : 867 - 871
[9] The anion of a phenyltris(alkylamino)phosphonium (PhTAP) salt as a chelating ligand: Synthesis and X-ray crystal structure of a 16-electron ruthenium(II) organometallic complex
Bailey, PJ
Grant, KJ
Parsons, S
[J]. ORGANOMETALLICS, 1998, 17 (04) : 551 - 555
[10] THE COORDINATION CHEMISTRY OF THE AMIDINE LIGAND
BARKER, J
KILNER, M
[J]. COORDINATION CHEMISTRY REVIEWS, 1994, 133 : 219 - 300

← 1 2 3 4 5 6 7 8 →