Pressure-density-temperature(p-ρ-T) surface of [C6mim][NTf2]

被引:73
作者
Esperanca, Jose M. S. S. [1 ]
Guedes, Henrique J. R. [2 ]
Lopes, Jose N. Canongia [1 ,3 ]
Rebelo, Luis Paulo N. [1 ]
机构
[1] Univ Nova Lisboa, Inst Tecnol Quim & Biol, ITQB2, P-2780901 Oeiras, Portugal
[2] Univ Nova Lisboa, Fac Ciencias & Tecnol, Dept Quim, REQUIMTE, P-2829516 Caparica, Portugal
[3] Inst Super Tecn, Ctr Quim Estrutural, P-1049001 Lisbon, Portugal
关键词
D O I
10.1021/je700628w
中图分类号
O414.1 [热力学];
学科分类号
摘要
In the framework of the IUPAC Project entitled "Thermodynamics of ionic liquids, ionic liquid mixtures, and the development of standardized systems", 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide, [C(6)mim][NTf2], was selected as the standard ionic liquid on which to perform round-robin measurements on a series of selected properties. In this work, the pressure, density, temperature (p, rho, T) surface was determined in the temperature range (293 to 338) K and up to a nominal pressure of 65 MPa. The isothermal compressibility and isobaric expansion coefficients were calculated from the (p, rho, T) data.
引用
收藏
页码:867 / 870
页数:4
相关论文
共 7 条
[1]   Phase transition and decomposition temperatures, heat capacities and viscosities of pyridinium ionic liquids [J].
Crosthwaite, JM ;
Muldoon, MJ ;
Dixon, JK ;
Anderson, JL ;
Brennecke, JF .
JOURNAL OF CHEMICAL THERMODYNAMICS, 2005, 37 (06) :559-568
[2]   Thermophysical and thermodynamic properties of ionic liquids over an extended pressure range:: [bmim][NTf2] and [hmim][NTf2] [J].
de Azevedo, RG ;
Esperança, JMSS ;
Szydlowski, J ;
Visak, ZP ;
Pires, PF ;
Guedes, HJR ;
Rebelo, LPN .
JOURNAL OF CHEMICAL THERMODYNAMICS, 2005, 37 (09) :888-899
[3]   Thermophysical and thermodynamic properties of 1-butyl-3-methylimidazolium tetrafluoroborate and 1-butyl-3-methylimidazolium hexafluorophosphate over an extended pressure range [J].
de Azevedo, RG ;
Esperança, JMSS ;
Najdanovic-Visak, V ;
Visak, ZP ;
Guedes, HJR ;
da Ponte, MN ;
Rebelo, LPN .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2005, 50 (03) :997-1008
[4]   A novel non-intrusive microcell for sound-speed measurements in liquids.: Speed of sound and thermodynamic properties of 2-propanone at pressures up to 160 MPa [J].
de Azevedo, RG ;
Szydlowski, J ;
Pires, PF ;
Esperança, JMSS ;
Guedes, HJR ;
Rebelo, LPN .
JOURNAL OF CHEMICAL THERMODYNAMICS, 2004, 36 (03) :211-222
[5]   Measurement of the viscosity, density, and electrical conductivity of 1-hexyl-3-methylimidazolium bis(trifluorosulfonyl)imide at temperatures between (288 and 433) K and pressures below 50 MPa [J].
Kandil, Mohamed E. ;
Marsh, Kenneth N. ;
Goodwin, Anthony R. H. .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2007, 52 (06) :2382-2387
[6]   Measurement of the viscosity and density of two reference fluids, with nominal viscosities at T=298 K and p=0.1 MPa of (16 and 29) mPa•s, at temperatures between (298 and 393) K and Pressures below 55 MPa [J].
Lundstrum, R ;
Goodwin, ARH ;
Hsu, K ;
Frels, M ;
Caudwell, DR ;
Trusler, JPM ;
Marsh, KN .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2005, 50 (04) :1377-1388
[7]   Density, viscosity, speed of sound, and electrolytic conductivity for the ionic liquid 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide and its mixtures with water [J].
Widegren, Jason A. ;
Magee, Joseph W. .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2007, 52 (06) :2331-2338