Diastereo- and enantioselective Diels-Alder reactions of 2-amino-1,3-dienes

被引：63

作者：

Enders, D

Meyer, O

机构：

[1] Institut für Organische Chemie, Rheinisch-Westfälische Technische Hochschule, D-52074 Aachen

来源：

LIEBIGS ANNALEN | 1996年 / 07期

关键词：

2-amino-1,3-dienes; enamines; cross conjugated; 4 + 2] cycloadditions; nitrocyclohexanones; 4-piperidinones; cycloheptandione derivatives; Danishefsky dienes;

D O I：

10.1002/jlac.199619960702

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The employment of 2-amino substituted 1,3-dienes in cycloaddition reactions has recently extended the scope of Diels-Alder methodologies. In this review, the preparation of a variety of 2-amino-1,3-dienes is presented, and the use of these cross conjugated enamines in normal as well as hetero Diels-Alder reactions is depicted. Diastereo- and enantioselective variations show new aspects for the preparation of cyclic carbonyl compounds in a highly stereoselective fashion. Further cyclisation reactions e.g. cyclopropanation reactions are also considered in this account.

引用

页码：1023 / 1035

页数：13

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