Copper(I) cyanide: A simple compound with a complicated structure and surprising room-temperature reactivity

被引：94

作者：

Hibble, SJ ^{[1
]}

Eversfield, SG

Cowley, AR

Chippindale, AM

机构：

[1] Univ Reading, Sch Chem, Reading RG6 6AD, Berks, England

[2] Chem Crystallog Lab, Oxford OX1 3PD, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 05期

关键词：

copper; cyanide; hydrothermal synthesis; polymorphism; structure elucidation;

D O I：

10.1002/anie.200352844

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Making Waves: Low-temperature CuCN has a curious wave structure (see picture Cu purple, C/N blue). Interconversion of this and the high-temperature, highly disordered form can be achieved at room-temperature via a novel zeolitic intermediate which is also structurally characterized.

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页码：628 / 630

页数：3

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