Elastic properties of methane hydrate at high pressures -: art. no. 054302

被引:10
作者
Baumert, J
Gutt, C
Krisch, M
Requardt, H
Müller, M
Tse, JS
Klug, DD
Press, W
机构
[1] Inst Max Von Laue Paul Langevin, F-38042 Grenoble, France
[2] Univ Kiel, Inst Expt & Angew Phys, Kiel, Germany
[3] European Synchrotron Radiat Facil, F-38043 Grenoble, France
[4] Natl Res Council Canada, Steacie Inst Mol Sci, Ottawa, ON, Canada
关键词
D O I
10.1103/PhysRevB.72.054302
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The longitudinal acoustic phonon dispersion of high-pressure methane hydrate structures MH-II and MH-III was determined by in situ high-pressure inelastic x-ray scattering. These results on powder samples, in conjunction with the previously established equation of state, allowed the derivation of the aggregate compressional and shear sound velocity, as well as the effective elastic and shear modulus. The elastic properties were found to differ substantially from the elastic properties of high pressure ice structures, while strongly reflecting the transition from a cage clathrate (MH-II) to a filled ice structure (MH-III).
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页数:5
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