Utilisation of cashew nut shell liquid from Anacardium occidentale as starting material for organic synthesis:: A novel route to lasiodiplodin from cardols

被引：39

作者：

dos Santos, ML ^{[1
]}

de Magalhaes, GC ^{[1
]}

机构：

[1] Univ Brasilia, Dept Quim, BR-70919970 Brasilia, DF, Brazil

来源：

JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY | 1999年 / 10卷 / 01期

关键词：

Cashew Nut Shell Liquid (CNSL); lasidiplodin; cardols;

D O I：

10.1590/S0103-50531999000100003

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

hs part of an ongoing program concerning utilisation of CNSL (Cashew Nut Shell Liquid) from Anacardium occidentale as starting material for the preparation of useful compounds, we describe the conversion of cardols (6-alkenylresorcinols) into lasiodiplodin, a naturally occurring 12-membered orsellinic acid type macrolide, which exhibits plant growth regulating and antileukemic properties.

引用

页码：13 / 20

页数：8

共 25 条

[1]

AGGARWAL JS, 1975, J COLOUR SOC, V1

[2] METABOLITES OF LASIODIPLODIA-THEOBROMAE [J].

ALDRIDGE, DC ;

GALT, S ;

GILES, D ;

TURNER, WB .

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1971, (09) :1623-&

[3]

ATTANASI O, 1979, CHIM IND-MILAN, V61, P718

[4]

BIRCH AJ, 1990, J CHEM SOC P1, V1, P1423

[5]

BRAUN M, 1990, LIEBIGS ANN CHEM, P513

[6] CHEMISTRY OF 1,3,5-TRIS(TRIMETHYLSILOXY)-1-METHOXYHEXA-1,3,5-TRIENE, A BETA-TRICARBONYL TRIANION EQUIVALENT [J].

CHAN, TH ;

STOSSEL, D .

JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (13) :2423-2428

[7] SILICON IN SYNTHESIS .18. SYNTHESIS OF METHYL KETONES AND (R)-(+)-FRONTALIN USING (1-CHLORO-1-(TRIMETHYLSILYL)ETHYL)LITHIUM FOR THE DIRECT CONVERSION OF ALDEHYDES AND KETONES INTO ALPHA,BETA-EPOXY TRIMETHYLSILANES [J].

COOKE, F ;

ROY, G ;

MAGNUS, P .

ORGANOMETALLICS, 1982, 1 (07) :893-897

[8]

COREY EJ, 1975, TETRAHEDRON LETT, P2647

[9] SELECTIVE OXIDATION OF ALDEHYDES TO CARBOXYLIC-ACIDS WITH SODIUM-CHLORITE HYDROGEN-PEROXIDE [J].

DALCANALE, E ;

MONTANARI, F .

JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (04) :567-569

[10] SIMPLE SYNTHETIC ROUTE TO LASIODIPLODIN [J].

DANISHEFSKY, S ;

ETHEREDGE, SJ .

JOURNAL OF ORGANIC CHEMISTRY, 1979, 44 (25) :4716-4717

← 1 2 3 →