Adsorption from a one-dimensional lattice gas and the Brunauer-Emmett-Teller equation

被引：24

作者：

Hill, TL

机构：

[1] Laboratory of Molecular Biology, Natl. Inst. Diabet. Digest. K., National Institutes of Health, Bethesda

[2] Santa Cruz, CA 95062

来源：

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA | 1996年 / 93卷 / 25期

关键词：

Ising model; reference system; Gibbs excess adsorption; Gibbs integral;

D O I：

10.1073/pnas.93.25.14328

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

An exact treatment of adsorption from a one-dimensional lattice gas is used to eliminate and correct a well-known inconsistency in the Brunauer-Emmett-Teller (B.E.T.) equation-namely Gibbs excess adsorption is not taken into account and the Gibbs integral diverges at the transition point, However, neither model should be considered realistic for experimental adsorption systems.

引用

页码：14328 / 14332

页数：5

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[9]

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