Bis[1-hydroxypyridine-2(1H)-thion-ato-S,O]copper(II)

被引:8
作者
Bond, AD
Feeder, N
Teat, SJ
Jones, W
机构
[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England
[2] CLRC Daresbury Lab, Warrington WA4 4AD, Cheshire, England
来源
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2001年 / 57卷 / 57期
关键词
D O I
10.1107/S0108270101012306
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Synchrotron radiation was used to determine the crystal structure of copper pyrithione from a microcrystalline fragment. The Cu complex was prepared by the combination of aqueous solution of CuCl2 and Na(PT) at room temperature. The resulting green precipitate was filtered and dried in air at room temperature. It was found that molecule adopts a trans-square-planar configuration, with the Cu atom sited at a crystallographic centre of inversion.
引用
收藏
页码:1157 / 1158
页数:2
相关论文
共 13 条
[1]   TABLES OF BOND LENGTHS DETERMINED BY X-RAY AND NEUTRON-DIFFRACTION .1. BOND LENGTHS IN ORGANIC-COMPOUNDS [J].
ALLEN, FH ;
KENNARD, O ;
WATSON, DG ;
BRAMMER, L ;
ORPEN, AG ;
TAYLOR, R .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (12) :S1-S19
[2]  
[Anonymous], 1996, CAMERON
[3]   STRUCTURAL CHARACTERIZATION OF BIS(N-OXOPYRIDINE-2-THIONATO)ZINC(III) [J].
BARNETT, BL ;
KRETSCHMAR, HC ;
HARTMAN, FA .
INORGANIC CHEMISTRY, 1977, 16 (08) :1834-1838
[4]  
Bruker, 2002, SMART SAINT
[5]   A new high-flux chemical and materials crystallography station at the SRS Daresbury .1. Design, construction and test results [J].
Cernik, RJ ;
Clegg, W ;
Catlow, CRA ;
BushnellWye, G ;
Flaherty, JV ;
Greaves, GN ;
Burrows, I ;
Taylor, DJ ;
Teat, SJ ;
Hamichi, M .
JOURNAL OF SYNCHROTRON RADIATION, 1997, 4 :279-286
[6]  
CHEN XT, 1991, POLYHEDRON, V10, P1651
[7]  
CLEGG W, 1997, LSCELL
[8]   STRUCTURE OF TRIS(2-MERCAPTOPYRIDINE 1-OXIDO)COBALT(III) ACETONITRILE SOLVATE [J].
HU, YH ;
WENG, LH ;
HUANG, LG ;
CHEN, XT ;
WU, DX ;
KANG, BS .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 :2655-2656
[9]  
Paulus W, 1993, MICROBICIDES PROTECT, DOI DOI 10.1007/978-94-011-2118-7
[10]  
SHELDRICK GM, 1997, SHELXL97 SHELXS97 SA