Aromatic gas oil cracking under realistic FCC conditions in a microriser reactor

被引:57
作者
Dupain, X
Gamas, ED
Madon, R
Kelkar, CP
Makkee, M
Moulijn, JA
机构
[1] Delft Univ Technol, Sect Reactor & Catalysis Engn, Fac Sci Appl, NL-2628 BL Delft, Netherlands
[2] Engelhard Corp, Iselin, NJ 08830 USA
关键词
fluid catalytic cracking; aromatics; kinetic modelling;
D O I
10.1016/S0016-2361(03)00077-2
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
A paraffinic hydrowax feed spiked with naphthalene, anthracene, and phenanthrene was cracked in a once-through microriser reactor at 575 degreesC and with a catalyst-to-oil (CTO) ratio of 4.8 g(cat) g(oil)(-1). The conversion by cracking reactions is limited to the paraffinic fraction of the feed and the alkyl groups associated with the benzene ring in aromatic compounds; the aromatic probes did not crack under the applied conditions, and in fact an additional amount of naphthalene was formed by complex dealkylation and hydrogen transfer reactions. The 'uncrackabilty' of aromatics was directly demonstrated by processing an aromatic gas oil, containing 33.3 wt% aromatics. Experiments were performed with residence times between 0.05 and 8.2 s, keeping the temperature (525 degreesC) and CTO ratio (5.5 g(cat) g(oil)(-1)) constant. The data was interpreted with a simplified first-order five-lump kinetic model, where approximately 19 wt% of the feed was found to be uncrackable. HCO (feedstock) conversion took mainly place during the first two seconds and coke was only formed during the first 50 ms of catalyst-oil contact. Gasoline was not overcracked to gas. Approximately 50 wt% of the LCO fraction was formed during this 50 ms and did not change thereafter. (C) 2003 Published by Elsevier Science Ltd.
引用
收藏
页码:1559 / 1569
页数:11
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