The inside story of fullerene anions:: A 3He NMR aromaticity probe

被引：30

作者：

Sternfeld, T

Saunders, M

Cross, RJ

Rabinovitz, M ^{[1
]}

机构：

[1] Hebrew Univ Jerusalem, Dept Organ Chem, IL-91904 Jerusalem, Israel

[2] Yale Univ, Dept Chem, New Haven, CT 06520 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 27期

关键词：

anions; aromaticity; fullerenes; helium; NMR spectroscopy;

D O I：

10.1002/anie.200351429

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Fullerene anions with helium atoms contained inside the cage exhibit degrees of aromaticity that can be predicted through the measurement of 3He chemical shifts (see picture). These chemical shifts help to demonstrate that the magnetic properties of fullerenes, and their anions, are not simply related to the number of carbon atoms or the number of electrons in the π system.

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页码：3136 / 3139

页数：4

相关论文

共 39 条

[1] Characterization of six isomers of [84]fullerene C84 by electrochemistry, electron spin resonance spectroscopy, and molecular energy levels calculations [J].

Azamar-Barrios, JA ;

Dennis, TJS ;

Sadhukan, S ;

Shinohara, H ;

Scuseria, GE ;

Pénicaud, A .

JOURNAL OF PHYSICAL CHEMISTRY A, 2001, 105 (19) :4627-4632

[2] ELECTRON-AFFINITIES OF HIGHER FULLERENES [J].

BOLTALINA, OV ;

SIDOROV, LN ;

BORSHCHEVSKY, AY ;

SUKHANOVA, EV ;

SKOKAN, EV .

RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 1993, 7 (11) :1009-1011

[3]

BUHL M, 1994, J AM CHEM SOC, V116, P6005

[4] Spherical aromaticity of fullerenes [J].

Bühl, M ;

Hirsch, A .

CHEMICAL REVIEWS, 2001, 101 (05) :1153-1183

[5] Endohedral chemical shifts in higher fullerenes with 72-86 carbon atoms [J].

Chen, ZF ;

Cioslowski, J ;

Rao, N ;

Moncrieff, D ;

Bühl, M ;

Hirsch, A ;

Thiel, W .

THEORETICAL CHEMISTRY ACCOUNTS, 2001, 106 (05) :364-368

[6] Isolation and characterization by 13C NMR spectroscopy of [84]fullerene minor isomers [J].

Dennis, TJS ;

Kai, T ;

Asato, K ;

Tomiyama, T ;

Shinohara, H ;

Yoshida, T ;

Kobayashi, Y ;

Ishiwatari, H ;

Miyake, Y ;

Kikuchi, K ;

Achiba, Y .

JOURNAL OF PHYSICAL CHEMISTRY A, 1999, 103 (44) :8747-8752

[7] Isolation and characterisation of the two major isomers of [84]fullerene (C84) [J].

Dennis, TJS ;

Kai, T ;

Tomiyama, T ;

Shinohara, H .

CHEMICAL COMMUNICATIONS, 1998, (05) :619-620

[8] FULLERENE ISOMERISM - ISOLATION OF C2-NU-C78 AND D3-C78 [J].

DIEDERICH, F ;

WHETTEN, RL ;

THILGEN, C ;

ETTL, R ;

CHAO, I ;

ALVAREZ, MM .

SCIENCE, 1991, 254 (5039) :1768-1770

[9] BEYOND C-60 - THE HIGHER FULLERENES [J].

DIEDERICH, F ;

WHETTEN, RL .

ACCOUNTS OF CHEMICAL RESEARCH, 1992, 25 (03) :119-126

[10] THE HIGHER FULLERENES - ISOLATION AND CHARACTERIZATION OF C76, C84, C90, C94, AND C70O, AN OXIDE OF D5H-C70 [J].

DIEDERICH, F ;

ETTL, R ;

RUBIN, Y ;

WHETTEN, RL ;

BECK, R ;

ALVAREZ, M ;

ANZ, S ;

SENSHARMA, D ;

WUDL, F ;

KHEMANI, KC ;

KOCH, A .

SCIENCE, 1991, 252 (5005) :548-551

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