Recent Progress of Rechargeable Batteries Using Mild Aqueous Electrolytes

被引：702

作者：

Huang, Jianhang ^{[1
,2
]}

Guo, Zhaowei ^{[1
]}

Ma, Yuanyuan ^{[1
]}

Bin, Duan ^{[1
]}

Wang, Yonggang ^{[1
]}

Xia, Yongyao ^{[1
]}

机构：

[1] Fudan Univ, iChEM Collaborat Innovat Ctr Chem Energy Mat, Shanghai Key Lab Mol Catalysis & Innovat Mat, Dept Chem,Inst New Energy, Shanghai 200433, Peoples R China

[2] Nanchang Hangkong Univ, Sch Mat Sci & Engn, Nanchang 330063, Jiangxi, Peoples R China

来源：

SMALL METHODS | 2019年 / 3卷 / 01期

基金：

中国国家自然科学基金;

关键词：

aqueous metal-ion batteries; aqueous zinc batteries; organic electrodes; water-in-salt" electrolytes; ZINC-ION BATTERY; IN-SALT ELECTROLYTE; ELECTROCHEMICAL ENERGY-STORAGE; HIGH-RATE ANODE; HIGH-CAPACITY; OPEN FRAMEWORK; HIGH-PERFORMANCE; CATHODE MATERIAL; POSITIVE ELECTRODE; MANGANESE-DIOXIDE;

D O I：

10.1002/smtd.201800272

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070305 [高分子化学与物理];

摘要：

Given the low cost, ease of fabrication, high safety, and environmental-friendly characteristics, aqueous rechargeable batteries using mild aqueous solutions as electrolytes (pH is close to 7) and a monovalent/multivalent metal ion as charge carrier, are attracting extensive attention for energy storage. However, accompanied by advantages of mild aqueous electrolyte mentioned above, there are some challenges that stand in the way of the development of these aqueous rechargeable batteries, such as the narrow stable electrochemical window of water, instability of electrode materials, undesired side reactions, etc. In recent years, a massive effort is devoted to overcoming the drawbacks, and some encouraging works have arisen. In this review, the latest advances of electrolyte and electrode materials in aqueous batteries based on monovalent ion (Li+, Na+, K+) and multivalent ion (Zn2+, Mg2+, Ca2+, Al3+) are briefly reviewed.

引用

页数：20

共 177 条

[1]

Electrochemical Zinc Intercalation in Lithium Vanadium Oxide: A High-Capacity Zinc-Ion Battery Cathode [J].