Organically-templated zinc and thorium sulfates with chain and layered structures

被引：18

作者：

Behera, JN

Rao, CNR

机构：

[1] Jawaharlal Nehru Ctr Adv Sci Res, Chem & Phys Mat Unit, Bangalore 560064, Karnataka, India

[2] Indian Inst Sci, Solid State & Struct Chem Unit, Bangalore 560012, Karnataka, India

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2005年 / 631卷 / 15期

关键词：

open-framework structures; zinc sulfate; thorium sulfate; hydro/solvothermal synthesis;

D O I：

10.1002/zaac.200500302

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Amine-templated zinc sulfates of the formulae, [Zn(SO4)(H2O)(2)(C10N2H8)] (1) and [C3N2H12][Zn(SO4)] (11) both with linear structures have been prepared under hydro/solvothermal conditions. Of these, I has the chain structure formed by ZnO(4)N(2)octahedra and SO4 tetrahedra, while It comprises ladders formed by corner-sharing four-membered rings. Amine-templated thorium sulfates of the formula [HN(CH2)(6)NH](2)[Th-2(SO4)(6)(H2O)2]-2H(2)O, (III) and [H2N(CH2)(4)NH2][Th-3(SO4)(7)(H2O)4(.)5H(2)O (IV) are also obtained under hydrothermal conditions. III has a sheet structure consisting of cages whereas IV has a two-dimensional structure derived from the connectivity of ladders.

引用

页码：3030 / 3036

页数：7

共 45 条

[1]

[Anonymous], 1998, ANGEW CHEM, V110, P48

[2] Two new diamine templated lanthanum sulfates, La2(H2O)2(C4H12N2)(SO4)4 and La2(H2O)2(C2H10N2)3(SO4)6•4H2O, with 3D and 2D crystal structures [J].