Crystals from concentrated glyme mixtures.: The single-crystal structure of LiClO4

被引：35

作者：

Henderson, WA

Brooks, NR

机构：

[1] Univ Minnesota, Dept Chem Engn & Mat Sci, Minneapolis, MN 55455 USA

[2] Univ Minnesota, Dept Chem, Xray Crystallog Lab, Minneapolis, MN 55455 USA

来源：

INORGANIC CHEMISTRY | 2003年 / 42卷 / 15期

关键词：

D O I：

10.1021/ic034518q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A procedure for the preparation of high-quality single crystals from concentrated glyme mixtures is presented. Anhydrous single crystals of LiNO3 and LiClO4 were prepared in this manner, and the single-crystal structure of LiClO4 (orthorhombic, Pnma, a = 8.6447(12) Angstrom, b = 6.8512(10) Angstrom, c = 4.8254(7) Angstrom, Z = 4) was determined as an example. This procedure is expected to be widely applicable for not only salts but also a wide range of other materials solvated by glymes.

引用

页码：4522 / 4524

页数：3

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