Synthesis and characterization of Ag/PVA nanocomposite by chemical reduction method

被引：365

作者：

Khanna, PK ^{[1
]}

Singh, N ^{[1
]}

Charan, S ^{[1
]}

Subbarao, VVVS ^{[1
]}

Gokhale, R ^{[1
]}

Mulik, UP ^{[1
]}

机构：

[1] C MET, Nanomat Lab, Pune 411008, Maharashtra, India

来源：

MATERIALS CHEMISTRY AND PHYSICS | 2005年 / 93卷 / 01期

关键词：

chemical synthesis; electronic materials; polymer; nanostructures;

D O I：

10.1016/j.matchemphys.2005.02.029

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Silver/poly(vinylalcohol) nanocomposites are prepared via in situ reduction of silver salt by employing two different reducing agents, namely, hydrazine hydrate and sodium formaldehyde sulfoxylate (SFS). Reduction of silver salt in aqueous PVA with SFS is done for the first ever time. The solutions and the films are characterized by using UV-vis, photoluminescence (PL), FTIR spectroscopy, XRD, SEM, TEM and thermal analysis. XRD patterns are consistent with that for cubic silver. SEM of the nanocomposite film shows uniform particles distribution within the film. The particle size is found to be less than 10 nm based on TEM. TGA showed that the composite has higher degradation temperature than the PVA alone. (c) 2005 Elsevier B.V. All rights reserved.

引用

收藏

页码：117 / 121

页数：5

相关论文

共 32 条

[1] Seeding of colloidal Au nanoparticle solutions. 2. Improved control of particle size and shape [J].

Brown, KR ;

Walter, DG ;

Natan, MJ .

CHEMISTRY OF MATERIALS, 2000, 12 (02) :306-313

[2] Synthesis of nanosized silver particles by chemical reduction method [J].

Chou, KS ;

Ren, CY .

MATERIALS CHEMISTRY AND PHYSICS, 2000, 64 (03) :241-246

[3] SYNTHESIS AND CHARACTERIZATION OF FINE AND MONODISPERSE SILVER PARTICLES OF UNIFORM SHAPE [J].

DUCAMPSANGUESA, C ;

HERRERAURBINA, R ;

FIGLARZ, M .

JOURNAL OF SOLID STATE CHEMISTRY, 1992, 100 (02) :272-280

[4] Production and luminescent properties of CdSe and US nanoparticle-polymer composites [J].

Firth, AV ;

Haggata, SW ;

Khanna, PK ;

Williams, SJ ;

Allen, JW ;

Magennis, SW ;

Samuel, IDW ;

Cole-Hamilton, DJ .

JOURNAL OF LUMINESCENCE, 2004, 109 (3-4) :163-172

[5] Two-electron sensitization: A new concept for silver halide photography [J].

Gould, IR ;

Lenhard, JR ;

Muenter, AA ;

Godleski, SA ;

Farid, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (48) :11934-11943

[6] Formation of silver dendrites under microwave irradiation [J].

He, R ;

Qian, XF ;

Yin, J ;

Zhu, ZK .

CHEMICAL PHYSICS LETTERS, 2003, 369 (3-4) :454-458

[7] FORMATION AND CATALYTIC FUNCTIONALITY OF SYNTHETIC POLYMER NOBLE METAL COLLOID [J].

HIRAI, H .

JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1979, A13 (05) :633-649

[8] Photoinduced conversion of silver nanospheres to nanoprisms [J].

Jin, RC ;

Cao, YW ;

Mirkin, CA ;

Kelly, KL ;

Schatz, GC ;

Zheng, JG .

SCIENCE, 2001, 294 (5548) :1901-1903

[9] PVA stabilized gold nanoparticles by use of unexplored albeit conventional reducing agent [J].

Khanna, PK ;

Gokhale, R ;

Subbarao, VVVS ;

Vishwanath, AK ;

Das, BK ;

Satyanarayana, CVV .

MATERIALS CHEMISTRY AND PHYSICS, 2005, 92 (01) :229-233

[10] Synthesis of fine US powder from direct in-situ reduction of sulphur and cadmium salts in aqueous N,N′-dimethylformamide [J].

Khanna, PK ;

Subbarao, VVVS .

MATERIALS LETTERS, 2004, 58 (22-23) :2801-2804

← 1 2 3 4 →