Potential curve of the 41Σ+ state of NaK by polarisation labelling spectroscopy

被引:9
作者
Jastrzebski, W
Nadyak, R
Kowalczyk, P
机构
[1] Polish Acad Sci, Inst Phys, PL-02668 Warsaw, Poland
[2] Univ Warsaw, Inst Expt Phys, PL-00681 Warsaw, Poland
关键词
D O I
10.1016/S0009-2614(03)00729-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The 4(I)Sigma(+) state of NaK molecule has been observed for the first time and studied by polarisation labelling spectroscopy technique. A total of 1567 rovibronic levels in this state were measured with an accuracy better than 0.1 cm(-1). The inverted perturbation approach method was used to construct the potential energy curve of the 4(I)Sigma(+) state. The irregular shape of the potential confirms earlier theoretical predictions. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:297 / 301
页数:5
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