Critical fluctuations of a binary fluid mixture confined in a porous medium

被引:39
作者
Formisano, F [1 ]
Teixeira, J
机构
[1] CEA, CNRS, Lab Leon Brillouin, F-91191 Gif Sur Yvette, France
[2] Ist Nazl Fis Mat, Sezione Firenze, I-50125 Florence, Italy
关键词
D O I
10.1007/s101890050001
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The have performed small angle neutron scattering experiments on the binary fluid mixture n-C6H14+n-C8F18 imbibed inside porous Vycor glass in the thermodynamic region corresponding to the bulk critical one. The resulting structure can be represented as the sum of a temperature dependent Lorentzian term and a term describing the interference between the porous matrix, a shell part richer in one component coating. the glass surface; and a core part richer in the other component. We observe critical fluctuations extending over distances markedly larger than the mean pore size.
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页码:1 / 4
页数:4
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