A rapid and efficient synthesis of quinone derivatives: Ru(II)- or Ir(I)-catalyzed hydrogen peroxide oxidation of phenols and methoxyarenes

被引：28

作者：

Iwasa, S ^{[1
]}

Fakhruddin, A

Widagdo, HS

Nishiyama, H

机构：

[1] Toyohashi Univ Technol, Sch Mat Sci, Toyohashi, Aichi 4418580, Japan

[2] Nagoya Univ, Dept Appl Chem, Grad Sch Engn, Nagoya, Aichi 4648603, Japan

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2005年 / 347卷 / 04期

关键词：

homogeneous catalysis; hydrogen peroxide; hydroquinones; N ligands; oxidation; ruthenium;

D O I：

10.1002/adsc.200404287

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Hydroquinone and methoxybenzene derivatives were catalytically oxidized promptly to the corresponding quinones in up to 99% yield. With a catalyst loading of 0.01 mol %, a maximum TON of 8.4 x 10(3) was attained in the case of Ru(II)-complex. Ru(II)(pybox-dh)(pydic) is able to enhance the hydrogen peroxide oxidation of substituted hydroquinones as well as methoxybenzenes, but Ir[(coe)(2)Cl](2) and Ir[(cod)Cl](2) were found to be effective catalysts only for the former substrates under similar oxidation conditions.

引用

收藏

页码：517 / 520

页数：4

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