Ink-jet printing of electron donor/acceptor blends: Towards bulk heterojunction solar cells

被引:59
作者
Marin, V
Holder, E
Wienk, MM
Tekin, E
Kozodaev, D
Schubert, US
机构
[1] Eindhoven Univ Technol, Lab Macromol Chem & Nanosci, NL-5600 MB Eindhoven, Netherlands
[2] Dutch Polymer Inst, NL-5600 MB Eindhoven, Netherlands
[3] Eindhoven Univ Technol, Lab Mol Mat & Nanosyst, NL-5600 MB Eindhoven, Netherlands
关键词
electron transfer; fluorescence; fullerenes; ink-jet printing; ruthenium(II)-containing polymers;
D O I
10.1002/marc.200400508
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
We illustrate the ink-jet printing of a thin-film library of donor/acceptor systems useful in bulk heterojunction solar cells and their characterization utilizing a UV-vis/fluorescence plate reader and an optical profilometer. In addition, the morphology of the films has been examined by atomic force microscopy (AFM). The ink-jet processing technology allows printing of arrays of different donor/acceptor compositions on one substrate as well as the subsequent fast optical screening of the electron transfer processes. The investigated films consist of blends of a poly(methyl methacrylate) polypyridyl ruthenium(II) copolymer (RuPMMA) as electron donor material (p-type) and C(60)fullerene (PC60BM) as well as heptyl viologen (C-7-V) derivatives as electron acceptor materials (n-type).
引用
收藏
页码:319 / 324
页数:6
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