Cu Nanoparticles Electrodeposited at Liquid-Liquid Interfaces: A Highly Efficient Catalyst for the Hydrogen Evolution Reaction

被引：57

作者：

Aslan, Emre ^{[1
]}

Patir, Imren Hatay ^{[1
]}

Ersoz, Mustafa ^{[1
]}

机构：

[1] Selcuk Univ, Dept Chem, TR-42031 Konya, Turkey

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2015年 / 21卷 / 12期

关键词：

copper; hydrogen evolution; liquid-liquid interface; nanoparticles; IMMISCIBLE ELECTROLYTE-SOLUTIONS; COPPER NANOPARTICLES; PD NANOPARTICLES; ELECTROCHEMICAL CHARACTERIZATION; LIQUID/LIQUID INTERFACES; POLARIZED INTERFACE; SILVER PARTICLES; NUCLEATION; ELECTROCATALYSIS; DEPOSITION;

D O I：

10.1002/chem.201406615

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

The electrochemical deposition of Cu nanoparticles with an average diameter of approximately 25-35nm has been reported at liquid-liquid interfaces by using the organic-phase electron-donor decamethylferrocene (DMFc). The electrodeposited Cu nanoparticles display excellent catalytic activity for the hydrogen evolution reaction (HER); this is the first reported catalytic effect of Cu nanoparticles at liquid-liquid interfaces.

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收藏

页码：4585 / 4589

页数：5

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