Solubility and diffusivity of solvents and nonsolvents in polysulfone and polyetherimide

被引:23
作者
Balashova, IM [1 ]
Danner, RP [1 ]
Puri, PS [1 ]
Duda, JL [1 ]
机构
[1] Penn State Univ, Ctr Study Polymer Solvent Syst, Dept Chem Engn, University Pk, PA 16802 USA
关键词
D O I
10.1021/ie001074m
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The inverse gas chromatography method was used for the investigation of the partition and diffusion coefficients of polysulfone and polyetherimide with NMP, gamma -butyrolactone, DMSO, acetic acid, propionic acid, THF, and water over a range of temperature from 200 to 270 degreesC. The weight-fraction infinite-dilution activity coefficients for the solvents, the Flory-Huggins interaction parameters, and the solubility parameters of the polymers are reported.
引用
收藏
页码:3058 / 3064
页数:7
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