Stoichiometric and catalytic activation of allyldimethylsilane.: Synthesis of [RuH2{η4-HSiMe2(CH=CHMe)}(PCy3)2]

被引：33

作者：

Delpech, F ^{[1
]}

Sabo-Etienne, S ^{[1
]}

Donnadieu, B ^{[1
]}

Chaudret, B ^{[1
]}

机构：

[1] CNRS, Chim Coordinat Lab, UPR 8241, F-31077 Toulouse 04, France

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 23期

关键词：

D O I：

10.1021/om9805180

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The bis(dihydrogen)ruthenium complex RuH2(H-2)(2)(PCy3)(2) (1) reacts with (CH2=CHCH2)Me2SiH to produce the title complex 4, a very reactive species stabilized by coordination of a vinylsilane ligand via Ru-(eta(2)-H-Si) and Ru-(eta(2)-C=C) bonds. 4 catalyzes silylation of (CH2=CHCH2)Me2SiH and redistribution at silicon render C2H4 pressure.

引用

页码：4926 / 4928

页数：3

共 27 条

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