Some applications of silica aerogels

被引:86
作者
Pajonk, GM [1 ]
机构
[1] Univ Lyon 1, CNRS, Lab Applicat Chim Environm, UMR 5634, F-69622 Villeurbanne, France
关键词
silica; aerogels; synthesis; properties; applications; SOL-GEL CHEMISTRY; PHYSICAL-PROPERTIES; SURFACE-AREA; MONOLITHICITY; PRECURSORS; CATALYSTS; PARAMETERS; INSULATION; TEXTURE;
D O I
10.1007/s00396-002-0814-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Silica aerogels are very highly divided materials which are synthesised through the association of a chemical step, the so-called sol-gel chemistry, with a physical step which is a particular way of drying the wet gel, namely under supercritical conditions with respect to the liquid phase filling its porosity. This drying process preserves the texture of the dry material: in practice it strongly reduces the pore collapse. The resulting hyperporous solids that have bulk densities of the same magnitude as air develop new and very interesting physical and even chemical properties. Owing to their poor chemical reactivity, very large surface areas (of the order of 1,000 m(2)/g), unusual porous volumes (greater than 95%), morphologies (monoliths or powders), optical properties (transparent, opaque or translucent), and very low thermal conductivity, they find high added-value applications in the physics of high-energy particles (Cherenkov emitters), transparent and superinsulating double windows, life and space science as well.
引用
收藏
页码:637 / 651
页数:15
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