Unexpected behavior of the methoxymethoxy group in the metalation/formylation reactions of 3-methoxymethoxyanisole

被引：8

作者：

Pocci, M

Bertini, V

Lucchesini, F

De Munno, A

Picci, N

Iemma, F

Alfei, S

机构：

[1] Univ Genoa, Dipartimento Chim & Tecnol Farmaceut & Alimentari, I-16147 Genoa, Italy

[2] Univ Pisa, Dipartimento Chim & Chim Ind, I-56126 Pisa, Italy

[3] Univ Calabria, Dipartimento Chim, I-87030 Arcavacata, Italy

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 07期

关键词：

D O I：

10.1016/S0040-4039(00)02230-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The formation of tetrasubstituted benzenes and doubly lithiated intermediates in metalation/formylation reactions of 3-methoxymethoxyanisole has been observed with the methoxylmethoxy group acting as a leaving group in some cases. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：1351 / 1354

页数：4

共 17 条

[1] 3,5-DICHLORO-4-PYRIDINECARBONITRILE AS A KEY REAGENT IN A SYNTHESIS OF COPPER-CONTAINING AMINE OXIDASE-INHIBITORS [J].