Efficient allylation of 4-silyloxyquinolinium triflates and other positively charged heteroaromatic systems

被引：17

作者：

Beifuss, U

Schniske, U

Feder, G

机构：

[1] Univ Gottingen, Inst Organ Chem, D-37077 Gottingen, Germany

[2] Univ Bayreuth, Organ Chem Lab, D-95447 Bayreuth, Germany

来源：

TETRAHEDRON | 2001年 / 57卷 / 06期

关键词：

allylation; quinolines; benzopyrans; sulfur heterocycles; tin and compounds; silicon and compounds;

D O I：

10.1016/S0040-4020(00)01066-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The regioselective allylation of 4-silyloxyquinolinium triflates with allyltri-n-butyltin has been performed to give 2-allyl-4-silyloxy-1,2-dihydroquinolines with excellent yields. Similiar results have been obtained with 4-silyloxy-l-benzopyrylium triflates and 4-silyloxy-1-benzothiopyrylium triflates. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：1005 / 1013

页数：9

共 30 条

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Beifuss, U
Taraschewski, M
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[10] Brocherieux-Lanoy S, 1999, SYNLETT, P405

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