Potential tuning and reaction control in the Diels-Alder reaction between cyclopentadiene and methyl acrylate in supercritical carbon dioxide

被引：31

作者：

Clifford, AA ^{[1
]}

Pople, K ^{[1
]}

Gaskill, WJ ^{[1
]}

Bartle, KD ^{[1
]}

Rayner, CM ^{[1
]}

机构：

[1] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1998年 / 94卷 / 10期

关键词：

D O I：

10.1039/a800873f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The ratio of endo- to exo-products in the Diels-Alder reaction between cyclopentadiene and methyl acrylate in supercritical carbon dioxide, plotted vs. the density of the medium, was found to go through a maximum at a density higher than the critical density. The effect can be explained in terms of the adjustment of the position of the nearest-neighbour solvent molecules with respect to the transition state. A theoretical discussion is given, which justifies this process being described as 'potential tuning'.

引用

页码：1451 / 1456

页数：6

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