Photocatalytic organic syntheses: selective cyclization of amino acids in aqueous suspensions

被引：48

作者：

Ohtani, B ^{[1
]}

Pal, B ^{[1
]}

Ikeda, S ^{[1
]}

机构：

[1] Hokkaido Univ, Ctr Catalysis Res, Sapporo, Hokkaido 0600811, Japan

来源：

CATALYSIS SURVEYS FROM ASIA | 2003年 / 7卷 / 2-3期

关键词：

photocatalysis; deaerated conditions; titanium(IV) oxide; cadmium(II) sulfide; platinum loading; pipecolinic acid; lysine; 2,6-diaminopimelic acid; piperidine-2,6-dicarboxylic acid;

D O I：

10.1023/A:1025389725637

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Photocatalytic reactions occurring at semiconductor particles/solution interfaces can be applied to organic syntheses. In this review article, examples of photocatalytic syntheses of cyclic amino acids by suspended semiconductor particles, e. g., titanium(IV) oxide or cadmium(II) sulfide are introduced and interpreted. Different from the photocatalytic decomposition of pollutants under aerobic conditions, selective conversion of organic compounds can be driven by the photocatalytic reactions under deaerated conditions.

引用

页码：165 / 176

页数：12

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