Core-shell MoO3-MoS2 Nanowires for Hydrogen Evolution: A Functional Design for Electrocatalytic Materials

被引：1207

作者：

Chen, Zhebo ^{[1
]}

Cummins, Dustin ^{[2
]}

Reinecke, Benjamin N. ^{[1
]}

Clark, Ezra ^{[2
]}

Sunkara, Mahendra K. ^{[2
]}

Jaramillo, Thomas F. ^{[1
]}

机构：

[1] Stanford Univ, Dept Chem Engn, Stanford, CA 94305 USA

[2] Univ Louisville, Dept Chem Engn, Louisville, KY 40292 USA

来源：

NANO LETTERS | 2011年 / 11卷 / 10期

关键词：

Electrochemistry; catalysis; molybdenum sulfide; nanowires; hydrogen evolution; PHOTOCATALYTIC H-2 EVOLUTION; SINGLE-CRYSTAL SURFACES; SOLAR-ENERGY; MOS2; WATER; MOLYBDENUM; OXIDATION; MECHANISM; PLATINUM; STORAGE;

D O I：

10.1021/nl2020476

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

We synthesize vertically oriented core-shell nanowires with substoichiometric MoO3 cores of similar to 20-50 nm and conformal MoS2 shells of similar to 2-5 nm. The core-shell architecture, produced by low-temperature sulfidization, is designed to utilize the best properties of each component material while mitigating their deficiencies. The substoichiometric MoO3 core provides a high aspect ratio foundation and enables facile charge transport, while the conformal MoS2 shell provides excellent catalytic activity and protection against corrosion in strong acids.

引用

页码：4168 / 4175

页数：8

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