UN213-:: A structurally characterized binary actinide heptaazide anion

被引：60

作者：

Crawford, MJ

Ellern, A

Mayer, P

机构：

[1] Univ Munich, Dept Chem & Biochem, D-81377 Munich, Germany

[2] Iowa State Univ, Dept Chem, Ames, IA 50011 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 48期

关键词：

azides; pseudohalides; structure elucidation; uranium;

D O I：

10.1002/anie.200502484

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

(Figure Presented) More stable than it seems: The binary uranium-nitrogen anion U(N3)73- was synthesized and characterized as the (Bu4N)3[U(N3)7] salt. The U(N3)73- ion is the first structurally characterized hepta-azide and is the first homoleptic azide of an actinide. The crystal structure shows a pentagonal-bipyramidal arrangement of the azide ligands around the central uranium(IV) atom (see structure; N: blue; U: green). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7874 / 7878

页数：5

共 71 条

[1]

CESIUM DIOXOPENTAKIS(THIOCYANATO)URANATE(VI) [J].

ALCOCK, NW ;

ROBERTS, MM ;

BROWN, D .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1982, 38 (NOV) :2870-2872

[2]

SIR97:: a new tool for crystal structure determination and refinement [J].

Altomare, A ;

Burla, MC ;

Camalli, M ;

Cascarano, GL ;

Giacovazzo, C ;

Guagliardi, A ;

Moliterni, AGG ;

Polidori, G ;

Spagna, R .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1999, 32 :115-119

[3]

[Anonymous], ANGEW CHEM

[4]

[Anonymous], ANGEW CHEM

[5]

[Anonymous], ANGEW CHEM

[6]

BAGNALL KW, 1972, MTP INT REV SCI, V7, P139

[7]

REPORT ON PSEUDOHALOGEN METALLIC COMPOUNDS .62. X-RAY STRUCTURE-ANALYSIS OF TETRAPHENYLARSONIUM TETRAAZIDOAURATE (III) [J].

BECK, W ;

NOTH, H .

CHEMISCHE BERICHTE-RECUEIL, 1984, 117 (01) :419-422

[8]

BECK W, 1966, Z NATURFORSCH PT B, VB 21, P811

[9]

DARSTELLUNG IR- UND ELEKTRONENSPEKTREN VON AZIDO-METALLKOMPLEXEN [J].

BECK, W ;

FEHLHAMM.WP ;

POLLMANN, P ;

SCHUIERE.E ;

FELDL, K .

CHEMISCHE BERICHTE-RECUEIL, 1967, 100 (07) :2335-&

[10]

Beck W, 2001, Z ANORG ALLG CHEM, V627, P1751, DOI 10.1002/1521-3749(200108)627:8<1751::AID-ZAAC1751>3.0.CO

← 1 2 3 4 5 6 7 8 →