Reversible anion binding in aqueous solution at a cationic heptacoordinate lanthanide centre: selective bicarbonate sensing by time-delayed luminescence

被引：113

作者：

Dickins, RS

Gunnlaugsson, T

Parker, D

Peacock, RD

机构：

[1] Univ Durham, Dept Chem, Durham DH1 3LE, England

[2] Univ Glasgow, Dept Chem, Glasgow G12 8QQ, Lanark, Scotland

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 16期

关键词：

D O I：

10.1039/a804255a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reversible displacement of up to two metal bound water molecules at a coordinately unsaturated, cationic lanthanide centre is signalled by increases in the luminescence intensity or lifetime of the emissive lanthanide: selective chelation of hydrogencarbonate is consistent with emission spectroscopic, ESMS and CPL measurements.

引用

页码：1643 / 1644

页数：2

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