When is template directed mineralization really template directed?

被引：58

作者：

DiMasi, E ^{[1
]}

Olszta, MJ

Patel, VM

Gower, LB

机构：

[1] Brookhaven Natl Lab, Dept Phys, Upton, NY 11973 USA

[2] Univ Florida, Dept Mat Sci & Engn, Gainesville, FL 32610 USA

[3] Univ Florida, Coll Med, Gainesville, FL 32611 USA

来源：

CRYSTENGCOMM | 2003年 / 5卷

关键词：

D O I：

10.1039/b309800a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In-situ synchrotron X-ray scattering clarifies the role of templating on calcium carbonate mineralization. Fatty acid monolayers are reorganized by Ca(2+) in the subphase, into structures with no epitaxial relation to CaCO(3) planes. Crystals are not oriented relative to the film; kinetics dominates polytype selection.

引用

收藏

页码：346 / 350

页数：5

相关论文

共 24 条

[1] CONTROL AND DESIGN PRINCIPLES IN BIOLOGICAL MINERALIZATION [J].

ADDADI, L ;

WEINER, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1992, 31 (02) :153-169

[2] Oriented growth of calcite controlled by self-assembled monolayers of functionalized alkanethiols supported on gold and silver [J].

Aizenberg, J ;

Black, AJ ;

Whitesides, GH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (18) :4500-4509

[3] Concentration-dependent formation mechanisms in mesophase silica-surfactant films [J].

Brennan, T ;

Hughes, AV ;

Roser, SJ ;

Mann, S ;

Edler, KJ .

LANGMUIR, 2002, 18 (25) :9838-9844

[4] Oriented crystallization of calcium carbonate under self-organized monolayers of amide-containing phospholipids [J].

Buijnsters, PJJA ;

Donners, JJJM ;

Hill, SJ ;

Heywood, BR ;

Nolte, RJM ;

Zwanenburg, B ;

Sommerdijk, NAJM .

LANGMUIR, 2001, 17 (12) :3623-3628

[5] Polymer-controlled growth rate of an amorphous mineral film nucleated at a fatty acid monolayer [J].

DiMasi, E ;

Patel, VM ;

Sivakumar, M ;

Olszta, MJ ;

Yang, YP ;

Gower, LB .

LANGMUIR, 2002, 18 (23) :8902-8909

[6]

DiMasi E, 2002, MATER RES SOC SYMP P, V711, P301

[7] COOPERATIVE ORGANIZATION OF INORGANIC-SURFACTANT AND BIOMIMETIC ASSEMBLIES [J].

FIROUZI, A ;

KUMAR, D ;

BULL, LM ;

BESIER, T ;

SIEGER, P ;

HUO, Q ;

WALKER, SA ;

ZASADZINSKI, JA ;

GLINKA, C ;

NICOL, J ;

MARGOLESE, D ;

STUCKY, GD ;

CHMELKA, BF .

SCIENCE, 1995, 267 (5201) :1138-1143

[8] Deposition of calcium carbonate films by a polymer-induced liquid-precursor (PILP) process [J].

Gower, LB ;

Odom, DJ .

JOURNAL OF CRYSTAL GROWTH, 2000, 210 (04) :719-734

[9] ORIENTED CRYSTALLIZATION OF CACO3 UNDER COMPRESSED MONOLAYERS .2. MORPHOLOGY, STRUCTURE AND GROWTH OF IMMATURE CRYSTALS [J].

HEYWOOD, BR ;

RAJAM, S ;

MANN, S .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1991, 87 (05) :735-743

[10] Observation of hexagonal crystalline diffraction from growing silicate films [J].

Holt, SA ;

Foran, GJ ;

White, JW .

LANGMUIR, 1999, 15 (07) :2540-2542