Oscillating Langmuir-Hinshelwood mechanisms

被引：59

作者：

Eiswirth, M

Burger, J

Strasser, P

Ertl, G

机构：

[1] Fritz-Haber-Institut der Max-Planck-Gesellschaft, D-14195 Berlin

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1996年 / 100卷 / 49期

关键词：

D O I：

10.1021/jp961688y

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Sufficient and necessary conditions for the occurrence of a Hopf bifurcation in chemical reaction mechanisms are presented using the formalism of stoichiometric networks. The conditions are applied to determine the mechanistic basis of chemical oscillations in isothermal surface reactions. Realistic examples are given for the different oscillatory mechanisms.

引用

收藏

页码：19118 / 19123

页数：6

相关论文

共 41 条

[21] SUPERSTRUCTURES OF THE CLEAN PT(100) AND IR(100) SURFACES [J].

HEILMANN, P ;

HEINZ, K ;

MULLER, K .

SURFACE SCIENCE, 1979, 83 (02) :487-497

[22]

HILDEBRAND M, PREPRINT

[23] BIFURCATION-ANALYSIS OF THE 3-VARIABLE MODEL FOR THE NO+CO REACTION ON PT SURFACES [J].

IMBIHL, R ;

FINK, T ;

KRISCHER, K .

JOURNAL OF CHEMICAL PHYSICS, 1992, 96 (08) :6236-6248

[24] OSCILLATORY KINETICS IN HETEROGENEOUS CATALYSIS [J].

IMBIHL, R ;

ERTL, G .

CHEMICAL REVIEWS, 1995, 95 (03) :697-733

[25] OSCILLATORY REACTIONS ON SINGLE-CRYSTAL SURFACES [J].

IMBIHL, R .

PROGRESS IN SURFACE SCIENCE, 1993, 44 (3-4) :185-343

[26] OSCILLATORY CO OXIDATION ON PT(110) - MODELING OF TEMPORAL SELF-ORGANIZATION [J].

KRISCHER, K ;

EISWIRTH, M ;

ERTL, G .

JOURNAL OF CHEMICAL PHYSICS, 1992, 96 (12) :9161-9172

[27] KINETIC OSCILLATIONS DURING THE CATALYTIC CO OXIDATION ON PD(110) - THE ROLE OF SUBSURFACE OXYGEN [J].

LADAS, S ;

IMBIHL, R ;

ERTL, G .

SURFACE SCIENCE, 1989, 219 (1-2) :88-106

[28] AUTONOMOUS BIFURCATIONS OF A SIMPLE BIMOLECULAR SURFACE-REACTION MODEL [J].

MCKARNIN, MA ;

ARIS, R ;

SCHMIDT, LD .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 1988, 415 (1849) :363-387

[29] PATTERN-FORMATION BY ADSORBATES WITH ATTRACTIVE LATERAL INTERACTIONS [J].

MIKHAILOV, A ;

ERTL, G .

CHEMICAL PHYSICS LETTERS, 1995, 238 (1-3) :104-109

[30] INTRINSICALLY UNSTABLE BEHAVIOR DURING THE OXIDATION OF CARBON-MONOXIDE ON PLATINUM [J].

RAZON, LF ;

SCHMITZ, RA .

CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 1986, 28 (01) :89-164

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