μ-3,4′-Bi-1,2,4-triazole-di-μ-chlorocuivre(II) monohydrate

被引:15
作者
Guédira, F
Idrissi, MS
Krautscheid, H
El Ammari, L
机构
[1] Fac Sci Rabat, Dept Chim, Lab Chim Solidde Appl LAF 501, Rabat, Morocco
[2] Fac Sci Rabat, Dept Chim, Lab Spectroscopie Infrarouge, Rabat, Morocco
[3] Univ Karlsruhe, Inst Anorgan Chem, D-76128 Karlsruhe, Germany
关键词
D O I
10.1107/S0108270103021516
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the title compound, mu-3,4'-bi-1,2,4-triazole-di-mu-chlorocopper(II) monohydrate, {[CuCl2(C4H4N6)].H2O}(n), the Cu atom is located in a distorted octahedron consisting of two N atoms and four Cl atoms. The structural unit is an infinite chain in which octahedral groups, connected by shared edges, are also linked by bitriazole molecules. The bitriazole ligand, the Cu atom and the water O atom all lie on independent twofold axes. The structure is held together by hydrogen bonds between the water molecules and the non-coordinated N atoms of the ligand, and by van der Waals forces.
引用
收藏
页码:M530 / M532
页数:3
相关论文
共 29 条
[1]  
Abbasoglu R, 1997, TURK J CHEM, V21, P144
[2]  
[Anonymous], 1996, CAMERON
[3]   CONFORMATIONAL-ANALYSIS OF 3,4'-BI-(1,2,4-TRIAZOLE) [J].
AOUIAL, M ;
VIALLEFONT, P ;
ELAMMARI, L .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 :1866-1868
[4]  
Castella-Ventura M, 1998, J RAMAN SPECTROSC, V29, P511, DOI 10.1002/(SICI)1097-4555(199806)29:6<511::AID-JRS271>3.0.CO
[5]  
2-J
[6]   1,2,4-TRIAZOLE COMPLEXES .5. CRYSTAL-STRUCTURE OF THE LAYERED COMPOUND POLY-BIS(THIOCYANATO-N)BIS-MU-(1,2,4-TRIAZOLE-N2,N4)COBALT(II) AND ITS ZINC(II) AND COPPER(II) ANALOGS [J].
ENGELFRIET, DW ;
DENBRINKER, W ;
VERSCHOOR, GC ;
GORTER, S .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1979, 35 (DEC) :2922-2927
[7]  
Farrugia L. J., 1999, J. Appl. Crystallogr, V32, P837, DOI [DOI 10.1107/S0021889899006020, 10.1107/S0021889899006020]
[8]   ON ENANTIOMORPH-POLARITY ESTIMATION [J].
FLACK, HD .
ACTA CRYSTALLOGRAPHICA SECTION A, 1983, 39 (NOV) :876-881
[9]  
Guedira F, 2001, CAN J ANAL SCI SPECT, V46, P1
[10]  
HAASNOOT JG, 1979, Z NATURFORSCH B, V34, P1500