One-pot separation of tea components through selective adsorption on pore-engineered nanocarbon, carbon nanocage

被引:142
作者
Ariga, Katsuhiko [1 ]
Vinu, Ajayan [1 ]
Miyahara, Masahiko [1 ]
Hill, Jonathan P. [1 ]
Mori, Toshiyuki [1 ]
机构
[1] Natl Inst Mat & Sci, Tsukuba, Ibaraki 3050044, Japan
关键词
D O I
10.1021/ja074870t
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Simple, economical, and toxic-solvent-free one-pot separation of tea components, such as catechin and tannic acids, has been demonstrated using the novel pore-engineered nanocarbon, carbon nanocage (CNC), with regularly arranged cage-type mesopores. The CNC materials possess larger specific surface areas and pore volumes than conventional mesoporous carbon, CMK-3, and also exhibit excellent adsorption capacities for a typical dye (Alizarin Yellow) and tea components (catechin and tannic acids) relative to activated carbon, CMK-3, and mesoporous silica SBA-15. Competitive adsorption of catechin and tannic acid to the CNC material results in highly selective adsorption of tannic acid (ca. 95%) using a very simple one-pot process.
引用
收藏
页码:11022 / +
页数:3
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