Development of a polyaniline-based optical ammonia sensor

被引:218
作者
Jin, Z [1 ]
Su, YX [1 ]
Duan, YX [1 ]
机构
[1] Univ Calif Los Alamos Natl Lab, Chem Sci & Technol Div, Los Alamos, NM 87545 USA
关键词
optical sensor; polyaniline; ammonia;
D O I
10.1016/S0925-4005(00)00636-5
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A polyaniline film was deposited on polyethylene surface by chemical oxidation of aniline monomer at room temperature. The ammonia gas sensing capabilities of the polyaniline film were studied using absorption spectroscopy method. A significant change was observed in the absorption spectra of the film after it was exposed to ammonia gas. The optical ammonia gas sensors have a response time of less than 15 s and a fast regeneration time of less than 2 min at room temperature. The sensors have a detection limit of 1 ppm (v/v) for ammonia. with a linear dynamic range from 180 to 18 000 ppm. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:75 / 79
页数:5
相关论文
共 13 条
[1]   An optical gas sensor based on polyaniline Langmuir-Blodgett films [J].
Agbor, NE ;
Cresswell, JP ;
Petty, MC ;
Monkman, AP .
SENSORS AND ACTUATORS B-CHEMICAL, 1997, 41 (1-3) :137-141
[2]   POLYANILINE THIN-FILMS FOR GAS-SENSING [J].
AGBOR, NE ;
PETTY, MC ;
MONKMAN, AP .
SENSORS AND ACTUATORS B-CHEMICAL, 1995, 28 (03) :173-179
[3]   Frequency counting interrogation techniques applied to gas sensor arrays [J].
Amrani, MEH ;
Payne, PA ;
Dowdeswell, RM ;
Hoffman, AD .
SENSORS AND ACTUATORS B-CHEMICAL, 1999, 57 (1-3) :75-82
[4]   Multi-frequency measurements of organic conducting polymers for sensing of gases and vapours [J].
Amrani, MEH ;
Payne, PA ;
Persaud, KC .
SENSORS AND ACTUATORS B-CHEMICAL, 1996, 33 (1-3) :137-141
[5]   The effect of initial conductivity and doping anions on gas sensitivity of conducting polypyrrole films to NH3 [J].
Brie, M ;
Turcu, R ;
Neamtu, C ;
Pruneanu, S .
SENSORS AND ACTUATORS B-CHEMICAL, 1996, 37 (03) :119-122
[6]   Optical sensing of pH based on polypyrrole films [J].
deMarcos, S ;
Wolfbeis, OS .
ANALYTICA CHIMICA ACTA, 1996, 334 (1-2) :149-153
[7]   IMMOBILIZATION OF GLUCOSE-OXIDASE IN FERROCENE-MODIFIED PYRROLE POLYMERS [J].
FOULDS, NC ;
LOWE, CR .
ANALYTICAL CHEMISTRY, 1988, 60 (22) :2473-2478
[8]   POLYMER FILM-BASED SENSORS FOR AMMONIA DETECTION [J].
KRUTOVERTSEV, SA ;
SOROKIN, SI ;
ZORIN, AV ;
LETUCHY, YA ;
ANTONOVA, OY .
SENSORS AND ACTUATORS B-CHEMICAL, 1992, 7 (1-3) :492-494
[9]   Ammonia sensors based on sensitive polyaniline films [J].
Kukla, AL ;
Shirshov, YM ;
Piletsky, SA .
SENSORS AND ACTUATORS B-CHEMICAL, 1996, 37 (03) :135-140
[10]   HIGH-FREQUENCY AC INVESTIGATION OF CONDUCTING POLYMER GAS SENSORS [J].
MUSIO, F ;
AMRANI, MEH ;
PERSAUD, KC .
SENSORS AND ACTUATORS B-CHEMICAL, 1995, 23 (2-3) :223-226