The first nonlayered metal sulfonate structure:: a 1-D Ba2+ network incorporating hydrophobic channels

被引：58

作者：

Yu, JO

Côté, AP

Enright, GD

Shimizu, GKH ^{[1
]}

机构：

[1] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada

[2] Natl Res Council Canada, Steacie Inst Mol Sci, Ottawa, ON K1A 0R6, Canada

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 04期

关键词：

D O I：

10.1021/ic000733k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The single-crystal X-ray structure of the first nonlayered metal sulfonate has been determined. Barium 2-pyridylethanesulfonate forms a one-dimensional framework with a backbone of SO3- and H2O-bridged Ba2+ columns. Pendant to these columns are 6-fold divergent organic groups that define hydrophobic channels (7.7 × 9.1 Å) and include guest ethyl acetate molecules. Thermal analysis results are also presented.

引用

页码：582 / 583

页数：2

共 24 条

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