Selective Oxidation of Glycerol by Highly Active Bimetallic Catalysts at Ambient Temperature under Base-Free Conditions

被引：239

作者：

Brett, Gemma L. ^{[1
]}

He, Qian ^{[2
]}

Hammond, Ceri ^{[1
]}

Miedziak, Peter J. ^{[1
]}

Dimitratos, Nikolaos ^{[1
]}

Sankar, Meenakshisundaram ^{[1
]}

Herzing, Andrew A. ^{[3
]}

Conte, Marco ^{[1
]}

Lopez-Sanchez, Jose Antonio ^{[1
]}

Kiely, Christopher J. ^{[2
]}

Knight, David W. ^{[1
]}

Taylor, Stuart H. ^{[1
]}

Hutchings, Graham J. ^{[1
]}

机构：

[1] Cardiff Univ, Cardiff Catalysis Inst, Sch Chem, Cardiff CF10 3AT, S Glam, Wales

[2] Lehigh Univ, Ctr Adv Mat & Nanotechnol, Bethlehem, PA 18015 USA

[3] NIST, Surface & Microanal Sci Div, Gaithersburg, MD 20899 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 43期

关键词：

alloys; gold; heterogeneous catalysis; nanoparticles; platinum; LIQUID-PHASE OXIDATION; ELECTRON-MICROSCOPY; GOLD CATALYSTS; PARTICLE-SIZE; CARBON; PD; NANOPARTICLES; ALCOHOLS;

D O I：

10.1002/anie.201101772

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Au-Pt alloy nanoparticles deposited on Mg(OH) 2 (see STEM-HAADF image) show high activity in the selective oxidation of polyols using molecular oxygen as oxidant at mild and base-free conditions. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：10136 / 10139

页数：4

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