Coordination-driven self-assembly of supramolecular cages: Heteroatom-containing and complementary trigonal prisms

被引：79

作者：

Kryschenko, YK

Seidel, SR

Muddiman, DC

Nepomuceno, AI

Stang, PJ

机构：

[1] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA

[2] Mayo Clin & Mayo Fdn, Dept Biochem & Mol Biol, Rochester, MN 55905 USA

[3] Mayo Clin & Mayo Fdn, WM Keck FT ICR Mass Spectrometry Lab, Rochester, MN 55905 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 32期

关键词：

D O I：

10.1021/ja030209n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The self-assembly of three nanoscopic prisms of approximate size 1 x 4 nm is reported. Tetrahedral carbon, silicon, and phosphorus were used as structure-defining elements in these coordination-based cages. A carbon-based assembly completes a pair of nanoscopic complementary 3-D structures. The formation of the structures is supported by multinuclear NMR, ESI FT-ICR mass spectrometry, and elemental analysis data.

引用

页码：9647 / 9652

页数：6

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