Enzyme Mimics Based Upon Supramolecular Coordination Chemistry

被引：680

作者：

Wiester, Michael J. ^{[1
,2
]}

Ulmann, Pirmin A. ^{[1
,2
]}

Mirkin, Chad A. ^{[1
,2
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

[2] Northwestern Univ, Int Inst Nanotechnol, Evanston, IL 60208 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 01期

基金：

美国国家科学基金会;

关键词：

coordination chemistry; enzyme mimics; host-guest systems; self-assembly; supramolecular chemistry; CYTOCHROME-C-OXIDASE; METAL-ORGANIC FRAMEWORK; HETEROGENEOUS ASYMMETRIC HYDROGENATION; PHOTOINDUCED ELECTRON-TRANSFER; INDUCED ALLOSTERIC TRANSITION; BIDENTATE PHOSPHORUS LIGANDS; DINUCLEAR ZN(II) CATALYST; DIELS-ALDER REACTIONS; H BOND ACTIVATION; ACTIVE-SITE MODEL;

D O I：

10.1002/anie.201000380

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Not just copies: Recent advances in supramolecular coordination chemistry have allowed chemists to synthesize macromolecular complexes that exhibit various properties intrinsic to enzymes. This Review focuses on structures inspired by properties and functions observed in enzymes rather than precise models of enzyme active sites. Many of the structures exhibit reactivity and specificity reminiscent of natural systems, and some of them have functions that exceed the natural systems which provided the inspiration for initially making them. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：114 / 137

页数：24

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