Determination of hydrogen concentration in ionic liquids and the effect (or lack of) on rates of hydrogenation

被引：160

作者：

Dyson, PJ ^{[1
]}

Laurenczy, G

Ohlin, CA

Vallance, J

Welton, T

机构：

[1] Ecole Polytech Fed Lausanne, BCH, Inst Chim Mol & Biol, CH-1015 Lausanne, Switzerland

[2] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 19期

关键词：

D O I：

10.1039/b308309h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The solubility of hydrogen and the corresponding Henry coefficients for 11 ionic liquids have been determined in situ at 100 atm H(2) pressure and are much lower than expected; attempts to correlate the solubility of hydrogen in the ionic liquids with the rate of reaction for the hydrogenation of benzene to cyclohexane in these solvents have been made.

引用

页码：2418 / 2419

页数：2

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