Urea and formamide as a mixed plasticizer for thermoplastic wheat flour

被引:60
作者
Ma, XF [1 ]
Yu, JG [1 ]
Ma, YB [1 ]
机构
[1] Tianjin Univ, Sch Sci, Tianjin 300072, Peoples R China
关键词
wheat flour; formamide; urea; thermoplastic;
D O I
10.1016/j.carbpol.2004.11.029
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Urea and formamide were used as a mixed plasticizer for preparing the thermoplastic wheat Flour (TPF) by a single screw extruder. Wheat flour granules were proved to transfer to a continuous phase by Scanning Electron Microscope (SEM). Rheology analysis illustrated that during the thermoplastic processing both the extruder screw speed and the processing temperature could effectively adjust the flow behavior of TPF. TG curves revealed that when the plasticizer weight content (PC) was under 40%, the whole of the plasticizer could be effectively bounded to wheat flour. TPF with 30% PC had the relatively good mechanical properties: The tensile strength, elongation at break, energy break and Young's modulus were 2.07 MPa, 44%, 0.35 N m and 20.1 MPa, respectively. X-ray analysis showed that the mixed plasticizer could effectively restrain the starch retrogradation of TPF. And water absorption testing showed that the lower PC was the better water resistance of TPF was. (c) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:111 / 116
页数:6
相关论文
共 21 条
[1]  
Averous L, 2000, J APPL POLYM SCI, V76, P1117, DOI 10.1002/(SICI)1097-4628(20000516)76:7<1117::AID-APP16>3.0.CO
[2]  
2-W
[3]   Enzymatic degradation and deacetylation of native and acetylated starch-based extruded blends [J].
Copinet, A ;
Bliard, C ;
Onteniente, JP ;
Couturier, Y .
POLYMER DEGRADATION AND STABILITY, 2001, 71 (02) :203-212
[4]   Thermoplastic starch-cellulosic fibers composites: preliminary results [J].
Curvelo, AAS ;
de Carvalho, AJF ;
Agnelli, JAM .
CARBOHYDRATE POLYMERS, 2001, 45 (02) :183-188
[5]   Characteristics of biodegradable Mater-Bi®-starch based foams as affected by ingredient formulations [J].
Fang, Q ;
Hanna, MA .
INDUSTRIAL CROPS AND PRODUCTS, 2001, 13 (03) :219-227
[6]   Extrusion of pectin/starch blends plasticized with glycerol [J].
Fishman, ML ;
Coffin, DR ;
Konstance, RP ;
Onwulata, CI .
CARBOHYDRATE POLYMERS, 2000, 41 (04) :317-325
[7]   Effect of sodium montmorillonite source on nylon 6/clay nanocomposites [J].
Fornes, TD ;
Hunter, DL ;
Paul, DR .
POLYMER, 2004, 45 (07) :2321-2331
[8]   The role of water during plasticization of native starches [J].
Hulleman, SHD ;
Janssen, FHP ;
Feil, H .
POLYMER, 1998, 39 (10) :2043-2048
[9]   Formamide as the plasticizer for thermoplastic starch [J].
Ma, XF ;
Yu, JG .
JOURNAL OF APPLIED POLYMER SCIENCE, 2004, 93 (04) :1769-1773
[10]  
Ma XF, 2004, CHINESE CHEM LETT, V15, P741