Multinuclear copper triethanolamine complexes as selective catalysts for the peroxidative oxidation of alkanes under mild conditions

被引：237

作者：

Kirillov, AM

Kopylovich, MN

Kirillova, MV

Haukka, M

da Silva, MFCG

Pombeiro, AJL

机构：

[1] Inst Super Tecn, Ctr Quim Estrutural, P-1049001 Lisbon, Portugal

[2] Univ Joensuu, Dept Chem, FIN-80101 Joensuu, Finland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 28期

关键词：

alkanes; biphasic catalysis; C-H activation; copper; oxidation;

D O I：

10.1002/anie.200500585

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Rich activity from a few coppers: Di-, tri-, tetra-, and polynuclear copper triethanolamine complexes are easily prepared and are selective and efficient catalysts for alkane peroxidative oxidation under mild conditions (see picture). © 2005; Wiley-VCH Verlag GmbH £ Co. KGaA.

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页码：4345 / 4349

页数：5

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