The role of metal nanoparticles in remote release of encapsulated materials

被引:462
作者
Skirtach, AG [1 ]
Dejugnat, C
Braun, D
Susha, AS
Rogach, AL
Parak, WJ
Möhwald, H
Sukhorukov, GB
机构
[1] Max Planck Inst Colloids & Interfaces, D-14424 Potsdam, Germany
[2] Univ Munich, Dept Phys, Ctr Nanosci & Photon, D-80799 Munich, Germany
[3] Univ Munich, Dept Phys, Optoelect Grp, D-80799 Munich, Germany
[4] Queen Mary Univ London, IRC, Dept Mat, London E1 4NS, England
关键词
D O I
10.1021/nl050693n
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Laser mediated remote release of encapsulated fluorescently labeled polymers from nanoengineered polyelectrolyte multilayer capsules containing gold sulfide core/gold shell nanoparticles in their walls is observed in real time on a single capsule level. We have developed a method for measuring the temperature increase and have quantitatively investigated the influence of absorption, size, and surface density of metal nanoparticles using an analytical model. Experimental measurements and numerical simulations agree with the model. The treatment presented in this work is of general nature, and it is applicable to any system where nanoparticles are used as absorbing centers. Potential biomedical applications are highlighted.
引用
收藏
页码:1371 / 1377
页数:7
相关论文
共 44 条
[1]   Nano-encapsulation of furosemide microcrystals for controlled drug release [J].
Ai, H ;
Jones, SA ;
de Villiers, MM ;
Lvov, YM .
JOURNAL OF CONTROLLED RELEASE, 2003, 86 (01) :59-68
[2]   Organization of 'nanocrystal molecules' using DNA [J].
Alivisatos, AP ;
Johnsson, KP ;
Peng, XG ;
Wilson, TE ;
Loweth, CJ ;
Bruchez, MP ;
Schultz, PG .
NATURE, 1996, 382 (6592) :609-611
[3]   Fabrication of a novel type of metallized colloids and hollow capsules [J].
Antipov, AA ;
Sukhorukov, GB ;
Fedutik, YA ;
Hartmann, J ;
Giersig, M ;
Möhwald, H .
LANGMUIR, 2002, 18 (17) :6687-6693
[4]   Plasmon resonance shifts of Au-coated Au2S nanoshells: Insight into multicomponent nanoparticle growth [J].
Averitt, RD ;
Sarkar, D ;
Halas, NJ .
PHYSICAL REVIEW LETTERS, 1997, 78 (22) :4217-4220
[5]   Trapping of DNA by thermophoretic depletion and convection [J].
Braun, D ;
Libchaber, A .
PHYSICAL REVIEW LETTERS, 2002, 89 (18) :1-188103
[6]  
Caruso F, 2001, ADV MATER, V13, P1090, DOI 10.1002/1521-4095(200107)13:14<1090::AID-ADMA1090>3.0.CO
[7]  
2-H
[8]   Polymer-stabilized gold nanoparticles and their incorporation into polymer matrices [J].
Corbierre, MK ;
Cameron, NS ;
Sutton, M ;
Mochrie, SGJ ;
Lurio, LB ;
Rühm, A ;
Lennox, RB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (42) :10411-10412
[9]   Fabrication of micro reaction cages with tailored properties [J].
Dähne, L ;
Leporatti, S ;
Donath, E ;
Möhwald, H .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (23) :5431-5436
[10]   Fuzzy nanoassemblies: Toward layered polymeric multicomposites [J].
Decher, G .
SCIENCE, 1997, 277 (5330) :1232-1237