Intramolecular cycloadditions of N-alkenoyl aryl azides

被引：14

作者：

Garanti, L

Molteni, G

Broggini, G

机构：

[1] Univ Milan, Dipartimento Chim Organ & Ind, I-20133 Milan, Italy

[2] Univ Insubria, Dipartimento Sci Chim Fis & Matemat, I-22100 Como, Italy

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 2001年 / 15期

关键词：

D O I：

10.1039/b102686k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Depending upon the reaction conditions, intramolecular cycloadditions of variously substituted N-alkenoyl aryl azides 4 give the [1,2,3]triazolobenzodiazepine 5, bridgehead aziridines 6 or imines 7. The dipolarophilic activity of the C=N double bond of the latter compounds is also exploited in the synthesis of [1,2,4]triazolobenzodiazepines 10 by means of nitrilimine cycloadditions.

引用

页码：1816 / 1819

页数：4

共 28 条

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[2]

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[3]

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[4]

Broggini G, 2000, HETEROCYCLES, V53, P917