Green photochemistry:: the solar-chemical 'photo-Friedel-Crafts acylation' of quinones

被引：60

作者：

Schiel, C

Oelgemöller, M

Ortner, J

Mattay, J

机构：

[1] Univ Bielefeld, Fak Chem, D-33501 Bielefeld, Germany

[2] JST, ERATO, Inoue Photochirogenesis Project, Toyonaka, Osaka 5600085, Japan

[3] Deutsches Zentrum Luft & Raumfahrt EV DLR, D-51170 Cologne, Germany

来源：

GREEN CHEMISTRY | 2001年 / 3卷 / 05期

关键词：

D O I：

10.1039/b106425h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The photoreactions between 1,4-quinones (1 and 4) and aldehydes (2 and 5), yielding acylated hydroquinones as sole products, were investigated under artificial and solar irradiation conditions. Three different solar reactors were used for the photochemical syntheses with sunlight (PROPHIS, CPC and a flat bed reactor), and the CPC system was found to be the most robust one in terms of weather dependence. The solar reactions can be easily performed on a half-kilogram scale using cheap and commercially available starting materials.

引用

页码：224 / 228

页数：5

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