Hydrothermal synthesis and structure of a bi-capped 1D chain (H2en)3H3O[Mo8V4O36(VO4)(VO)2]•4H2O

被引：20

作者：

Luan, GY ^{[1
]}

Wang, EB ^{[1
]}

Han, ZB ^{[1
]}

Li, YG ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Changchun 130024, Jinlin, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2001年 / 4卷 / 10期

基金：

中国国家自然科学基金;

关键词：

heteropolymolybdovanadates; 1D chain; crystal structure; hydrothermal synthesis;

D O I：

10.1016/S1387-7003(01)00250-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound, (H(2)en)(3)H3O[Mo8V4O36(VO4)(VO)(2)]. 4H(2)O, Was hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction. The crystal data: monoclinic, P2(1/c), a = 19.804(4) Angstrom, b = 20.634(4) Angstrom, c = 11.920(2) Angstrom, beta = 94.76(3)degrees. X-ray crystallographic study showed that the crystal structure was constructed by bi-capped alpha -Keggin fragment {Mo8C7O42} units linked together by V-O-V bonds to a chain. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：541 / 543

页数：3

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