Trimethylsilyl cyanide addition to carbonyl compounds under neutral condition catalyzed by iodine

被引：9

作者：

Azizi, N ^{[1
]}

Saidi, MR ^{[1
]}

机构：

[1] Sharif Univ Technol, Dept Chem, Tehran, Iran

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2003年 / 178卷 / 10期

关键词：

carbonyl compound; cyanohydrin trimethylsilyl ether; iodine; trimethylsilyl cyanide; BOND FORMATION; KETONES; ALDEHYDES; ACID; NUCLEOPHILES; EFFICIENT; ACETALS;

D O I：

10.1080/713744569

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of trimethylsilyl cyanide with aliphatic or aromatic aldehydes and ketones in the presence of a catalytic amount of elemental iodine produced the corresponding cyanohydrin trimethylsilyl ethers in very short time and high yields.

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页码：2111 / 2115

页数：5

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