Luminescence and thermal stability of sodium tris(pyridine dicarboxylate) terbate(III) complex incorporated in silica matrix by sol-gel method

被引:11
作者
An, BL
Ye, JQ
Gong, ML [1 ]
Yin, XH
Yang, YS
Zheng, XG
Deng, SZ
Xu, NZ
机构
[1] Zhongshan Univ, Guangdong Province Key Lab Display Mat & Technol, Guangzhou 510275, Peoples R China
[2] Zhongshan Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China
[3] Guangxi Univ National, Dept Chem, Nanning 530006, Peoples R China
关键词
composites; sol-gel chemistry; luminescence;
D O I
10.1016/S0025-5408(01)00618-3
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A terbium(III) complex, Na3Tb(DPA)(3). 9H(2)O. where H,DPA is 2,6-dicarboxy pyridine acid. has been synthesized and incorporated into silica gel by sol-gel method to obtain a composite material, SiO2:Na3Tb(DPA)(3), Photoluminescent properties of SiO2:Na3Tb(DPA)(3) composite were studied after heat treatments between room temperature and 600 degreesC. The strong green emission of the composite material was intensified by heat-treatment under appropriate conditions. The effects of the dopant concentration and heat-treatment on the luminescence for the composite material have been examined. The results indicate that SiO2:Na(3)To(DPA)(3) composite material possesses high thermal stability with intense green fluorescence, and may be applied as a potential luminescent material. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1335 / 1346
页数:12
相关论文
共 18 条
  • [1] THE ROLE OF N,N-DIMETHYLFORMAMIDE, A DCCA, IN THE FORMATION OF SILICA-GEL MONOLITHS BY SOL-GEL METHOD
    ADACHI, T
    SAKKA, S
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 1988, 99 (01) : 118 - 128
  • [2] Chen G Z, 1990, FLUORESCENCE ANAL ME, P15
  • [3] Nanostructure magneto-optical thin films of rare earth (RE = Gd, Tb, Dy) doped cobalt spinel by sol-gel synthesis
    Cheng, FX
    Liao, CS
    Kuang, JF
    Xu, ZG
    Yan, CH
    Chen, LY
    Zhao, HB
    Liu, Z
    [J]. JOURNAL OF APPLIED PHYSICS, 1999, 85 (05) : 2782 - 2786
  • [4] Spectroscopic characterization of Eu3+-doped inorganic and alkoxide sol-gel derived fluorozirconate glass and zirconium fluoride gels
    Dejneka, M
    Snitzer, E
    Riman, RE
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 1996, 202 (1-2) : 23 - 34
  • [5] LUMINESCENCE PROPERTY OF THE TERBIUM BIPYRIDYL COMPLEX INCORPORATED IN SILICA MATRIX BY A SOL-GEL METHOD
    JIN, T
    TSUTSUMI, S
    DEGUCHI, Y
    MACHIDA, KI
    ADACHI, GY
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (10) : L195 - L197
  • [6] Preparation and luminescence characteristics of the europium and terbium complexes incorporated into a silica matrix using a sol-gel method
    Jin, T
    Tsutsumi, S
    Deguchi, Y
    Machida, K
    Adachi, G
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 1997, 252 (1-2) : 59 - 66
  • [7] Luminescence properties of lanthanide complexes and their silica-based composites
    Jin, T
    Inoue, S
    Machida, K
    Adachi, GY
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 1998, 265 (1-2) : 234 - 239
  • [8] Photo-properties of rare earth ion (Er3+, Eu3+ and Sm3+)-doped alumina films prepared by the sol-gel method
    Kurokawa, Y
    Ishizaka, T
    Ikoma, T
    Tero-Kubota, S
    [J]. CHEMICAL PHYSICS LETTERS, 1998, 287 (5-6) : 737 - 741
  • [9] COMPARATIVE-STUDY OF CA4Y6(SIO4)(6)O-A PHOSPHORS PREPARED BY SOL-GEL AND DRY METHODS (A=PB2+,EU3+, TB3+,DY3+)
    LIN, J
    SU, Q
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 1995, 5 (04) : 603 - 606
  • [10] LUMINESCENCE BEHAVIOR OF EUROPIUM COMPLEXES IN SOL-GEL DERIVED HOST MATERIALS
    MATTHEWS, LR
    KNOBBE, ET
    [J]. CHEMISTRY OF MATERIALS, 1993, 5 (12) : 1697 - 1700