Luminescence and thermal stability of sodium tris(pyridine dicarboxylate) terbate(III) complex incorporated in silica matrix by sol-gel method
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An, BL
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机构:Zhongshan Univ, Guangdong Province Key Lab Display Mat & Technol, Guangzhou 510275, Peoples R China
An, BL
Ye, JQ
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机构:Zhongshan Univ, Guangdong Province Key Lab Display Mat & Technol, Guangzhou 510275, Peoples R China
Ye, JQ
Gong, ML
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Zhongshan Univ, Guangdong Province Key Lab Display Mat & Technol, Guangzhou 510275, Peoples R ChinaZhongshan Univ, Guangdong Province Key Lab Display Mat & Technol, Guangzhou 510275, Peoples R China
Gong, ML
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Yin, XH
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机构:Zhongshan Univ, Guangdong Province Key Lab Display Mat & Technol, Guangzhou 510275, Peoples R China
Yin, XH
Yang, YS
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Yang, YS
Zheng, XG
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Zheng, XG
Deng, SZ
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Deng, SZ
Xu, NZ
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Xu, NZ
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[1] Zhongshan Univ, Guangdong Province Key Lab Display Mat & Technol, Guangzhou 510275, Peoples R China
[2] Zhongshan Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China
[3] Guangxi Univ National, Dept Chem, Nanning 530006, Peoples R China
A terbium(III) complex, Na3Tb(DPA)(3). 9H(2)O. where H,DPA is 2,6-dicarboxy pyridine acid. has been synthesized and incorporated into silica gel by sol-gel method to obtain a composite material, SiO2:Na3Tb(DPA)(3), Photoluminescent properties of SiO2:Na3Tb(DPA)(3) composite were studied after heat treatments between room temperature and 600 degreesC. The strong green emission of the composite material was intensified by heat-treatment under appropriate conditions. The effects of the dopant concentration and heat-treatment on the luminescence for the composite material have been examined. The results indicate that SiO2:Na(3)To(DPA)(3) composite material possesses high thermal stability with intense green fluorescence, and may be applied as a potential luminescent material. (C) 2001 Elsevier Science Ltd. All rights reserved.