Controlling side-chain density of electron donating polymers for improving their packing structure and photovoltaic performance

被引:40
作者
Cho, Chul-Hee [1 ]
Kang, Hyunbum [1 ]
Kang, Tae Eui [1 ]
Cho, Han-Hee [1 ]
Yoon, Sung Cheol [2 ]
Jeon, Moon-Kook [3 ]
Kim, Bumjoon J. [1 ]
机构
[1] Korea Adv Inst Sci & Technol, Dept Chem & Biomol Engn, Taejon 305701, South Korea
[2] Korea Res Inst Chem Technol, Adv Mat Div, Taejon 305600, South Korea
[3] Korea Res Inst Chem Technol, Ctr Drug Discovery Platform Technol, Taejon 305600, South Korea
关键词
SOLAR-CELLS; EFFICIENCY;
D O I
10.1039/c1cc10184f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A simple and efficient approach of controlling the side-chain density in the electron donating polymers has been demonstrated to tune their 3-D packing structure and HOMO level, which increases the hole mobility and V-oc values, thus improving the solar cell performance.
引用
收藏
页码:3577 / 3579
页数:3
相关论文
共 17 条
[1]   X-ray scattering study of thin films of poly(2,5-bis(3-alkylthiophen-2-yl)thieno[3,2-b]thiophene) [J].
Chabinyc, Michael L. ;
Toney, Michael F. ;
Kline, R. Joseph ;
McCulloch, Iain ;
Heeney, Martin .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (11) :3226-3237
[2]   X-RAY-DIFFRACTION STUDY OF OCTYLPHENYL-SUBSTITUTED POLYTHIOPHENE [J].
FELL, HJ ;
SAMUELSEN, EJ ;
MARDALEN, J ;
ANDERSSON, MR .
SYNTHETIC METALS, 1995, 69 (1-3) :283-284
[3]   Correlation between oxidation potential and open-circuit voltage of composite solar cells based on blends of polythiophenes/fullerene derivative [J].
Gadisa, A ;
Svensson, M ;
Andersson, MR ;
Inganäs, O .
APPLIED PHYSICS LETTERS, 2004, 84 (09) :1609-1611
[4]   Laminated fabrication of polymeric photovoltaic diodes [J].
Granström, M ;
Petritsch, K ;
Arias, AC ;
Lux, A ;
Andersson, MR ;
Friend, RH .
NATURE, 1998, 395 (6699) :257-260
[5]   All-Polymer Photovoltaic Devices of Poly(3-(4-n-octyl)-phenylthiophene) from Grignard Metathesis (GRIM) Polymerization [J].
Holcombe, Thomas W. ;
Woo, Claire H. ;
Kavulak, David F. J. ;
Thompson, Barry C. ;
Frechet, Jean M. J. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (40) :14160-+
[6]   An Easy and Effective Method To Modulate Molecular Energy Level of Poly(3-alkylthiophene) for High-Voc Polymer Solar Cells [J].
Hou, Jianhui ;
Chen, Teresa L. ;
Zhang, Shaoqing ;
Huo, Lijun ;
Sista, Srinivas ;
Yang, Yang .
MACROMOLECULES, 2009, 42 (23) :9217-9219
[7]   Synthesis of a Low Band Gap Polymer and Its Application in Highly Efficient Polymer Solar Cells [J].
Hou, Jianhui ;
Chen, Hsiang-Yu ;
Zhang, Shaoqing ;
Chen, Ruby I. ;
Yang, Yang ;
Wu, Yue ;
Li, Gang .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (43) :15586-+
[8]   Critical role of side-chain attachment density on the order and device performance of polythiophenes [J].
Kline, R. Joseph ;
DeLongchamp, Dean M. ;
Fischer, Daniel A. ;
Lin, Eric K. ;
Richter, Lee J. ;
Chabinyc, Michael L. ;
Toney, Michael F. ;
Heeney, Martin ;
McCulloch, Iain .
MACROMOLECULES, 2007, 40 (22) :7960-7965
[9]   Fabrication and processing of polymer solar cells: A review of printing and coating techniques [J].
Krebs, Frederik C. .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2009, 93 (04) :394-412
[10]   For the Bright Future-Bulk Heterojunction Polymer Solar Cells with Power Conversion Efficiency of 7.4% [J].
Liang, Yongye ;
Xu, Zheng ;
Xia, Jiangbin ;
Tsai, Szu-Ting ;
Wu, Yue ;
Li, Gang ;
Ray, Claire ;
Yu, Luping .
ADVANCED MATERIALS, 2010, 22 (20) :E135-+