UV-Vis microspectroscopy: Probing the initial stages of supported metal oxide catalyst preparation

被引：53

作者：

van de Water, LG ^{[1
]}

Bergwerff, JA ^{[1
]}

Nijhuis, TA ^{[1
]}

de Jong, KP ^{[1
]}

Weckhuysen, BM ^{[1
]}

机构：

[1] Univ Utrecht, Debye Inst, Dept Inorgan Chem & Catalysis, NL-3508 TB Utrecht, Netherlands

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 14期

关键词：

D O I：

10.1021/ja044460u

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A UV-vis microspectroscopy methodology for monitoring the speciation and macrodistribution of catalyst-precursor species inside catalyst-support bodies at the initial stages of catalyst preparation has been developed. The setup is based upon optical-fiber technology and allows spatially resolved analysis of bisected catalyst bodies. The potential of this tool is demonstrated by two pore-volume impregnation studies involving Ni2+ d-d transition bands and Cr6+ charge-transfer bands. Copyright © 2005 American Chemical Society.

引用

页码：5024 / 5025

页数：2

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