High resolution solid state NMR spectroscopy in surface organometallic chemistry:: access to molecular understanding of active sites of well-defined heterogeneous catalysts

被引：82

作者：

Blanc, Frederic ^{[1
]}

Coperet, Christophe ^{[1
]}

Lesage, Anne ^{[2
]}

Emsley, Lyndon ^{[2
]}

机构：

[1] Univ Lyon, Inst Chim Lyon,CNRS LC2P2, Equipe Chim Organomet Surface, CPE Lyon, F-69616 Villeurbanne, France

[2] Ecole Normale Super Lyon, Chim Lab, UMR 5532, F-69364 Lyon 07, France

来源：

CHEMICAL SOCIETY REVIEWS | 2008年 / 37卷 / 03期

关键词：

D O I：

10.1039/b612793m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Recent advances in solid state NMR spectroscopy have made possible the understanding of surface species and active sites of heterogeneous catalysts at a molecular level. This tutorial review describes solid state NMR spectroscopy, what are the possible techniques to obtain high resolution and 2D spectra ( structural information), and what are their applications in the context of well-defined heterogeneous catalysts prepared by surface organometallic chemistry.

引用

页码：518 / 526

页数：9

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